| Atomic Number: |
103 |
| Atomic Symbol: |
Lr |
| Atomic Weight: |
262 |
| Electron Configuration: |
[Rn]7s25f146d1 |
Lawrencium
is a synthetic "rare earth metal" which does not
occur in the environment. This member of the 5f transition
elements (actinide series) was discovered in March 1961
by A. Ghiorso, T. Sikkeland, A.E. Larsh, and R.M. Latimer.
A 3-Mg californium target, consisting of a mixture of isotopes
of mass number 249, 250, 251, and 252, was bombarded with
either 10B or 11B. The electrically charged transmutation
nuclei recoiled with an atmosphere of helium and were collected
on a thin copper conveyor tape which was then moved to place
collected atoms in front of a series of solid-state detectors.
The isotope of element 103 produced in this way decayed
by emitting an 8.6 MeV alpha particle with a half-life of
8 s.
In
1967, Flerov and associates at the Dubna Laboratory reported
their inability to detect an alpha emitter with a half-life
of 8 s which was assigned by the Berkeley group to 257-103.
This assignment has been changed to 258Lr or 259Lr.
In
1965, the Dubna workers found a longer-lived lawrencium
isotope, 256Lr, with a half-life of 35 s. In 1968, Thiorso
and associates at Berkeley used a few atoms of this isotope
to study the oxidation behavior of lawrencium. Using solvent
extraction techniques and working very rapidly, they extracted
lawrencium ions from a buffered aqueous solution into
an organic solvent -- completing each extraction in about
30 s. Lawrencium behaves differently from dipositive nobelium
and more like the tripositive elements earlier in the
actinide series.