| Atomic Number: |
105 |
| Atomic Symbol: |
Db |
| Atomic Weight: |
262 |
| Electron Configuration: |
[Rn]7s25f146d3
|
In 1967
G.N. Flerov reported that a Soviet team working at the Joint
Institute for Nuclear Research at Dubna may have produced
a few atoms of 260-105 and 261-105 by bombarding 243Am with
22Ne. The evidence was based on time-coincidence measurements
of alpha energies.
In
1970 Dubna scientists synthesized Element 105 and, by
the end of April 1970, "had investigated all the
types of decay of the new element and had determined its
chemical properties," according to a report in 1970.
The Soviet group had not proposed a name for 105. In late
April 1970, it was announced that Ghiorso, Nurmia, Haris,
K.A.Y. Eskola, and P.L. Eskola, working at the University
of California at Berkeley, had positively identified element
105. The discovery was made by bombarding a target of
249Cf with a beam of 84 MeV nitrogen nuclei in the Heavy
Ion Linear Accelerator (HILAC). When a 15N nuclear is
absorbed by a 249Cf nucleus, four neutrons are emitted
and a new atom of 260-105 with a half-life of 1.6 s is
formed. While the first atoms of Element 105 are said
to have been detected conclusively on March 5, 1970, there
is evidence that Element 105 had been formed in Berkeley
experiments a year earlier by the method described.
Ghiorso
and his associates have attempted to confirm Soviet findings
by more sophisticated methods without success. The Berkeley
Group proposed the name hahnium -- after the late German
scientist Otto Hahn (1879-1968) -- and symbol Ha. However,
the International Union of Pure and Applied Chemistry
panel members in 1977 recommended that element 105 be
named to Dubnium (symbol Db) after the site of the Joint
Institute for Nuclear Research in Russia. Unfortunately,
the name hahnium will not be used again according to the
rules for naming new elements. Some scientists still use
the earlier name of hahnium because it had been used for
about 25 years.
Isotopes
In
October 1971, it was announced that two new isotopes of
element 105 were synthesized with the heavy ion linear
accelerator by A. Ghiorso and co-workers a Berkeley. Element
261-105 was produced both by bombarding 250Cf with 15N
and by bombarding 249Bk with 16O. The isotope emits 8.93-MeV
alpha particles and decays to 257Lr with a half-life of
about 1.8 s. Element 262-105 was produced by bombarding
249Bk with 18O. It emits 8.45 MeV alpha particles and
decays to 258Lr with a half-life of about 40 s. Seven
isotopes of element 105 (unnilpentium) are now recognized.